Gas ionizer devoid of coaxial electrodes

ABSTRACT

Apparatus for ionizing gases at very low pressures comprising inner and outer electrodes wherein the inner electrode is substantially circular in cross section and the outer electrode surrounding the inner electrode may be other than a figure of revolution or may be eccentrically positioned with respect to the inner electrode which inner electrode is less in length than two times the length of the surrounding outer electrode and is spaced therefrom a distance which is greater than the diameter of the inner electrode for a distance of not less than two-thirds the length of the surrounding outer electrode.

United States Patent Barney Carr, deceased late of Colorada Springs, Colo. by Elisabeth Helen Carr, administratrix [2]] Appl No. 742,960

[22] Filed June 24, 1968 [72] Inventor [45] Patented Oct. 19, 1971 [73] Assignee Kaman Sciences Corporation Colorado Springs, Colo.

Continuation of application Ser. No. 404,535, Oct. 16, 1964,

[54] GAS lONlZER DEVOID OF COAXlAL ELECTRODES 19 Claims, 10 Drawing Figs.

[52] US. Cl 250/845, 3l3/6l,3l5Il1l,328/25l [S1] lnt.Cl G21g3/04 [50] Field of Search 250/845;

///6// VOZ 7/165 [56] References Cited UNITED STATES PATENTS 3,156,842 11/1964 McClure Primary Examiner-Archie R. Borchelt Assistant ExaminerDavis L. Willis Attorney-Anderson, Spangle & Wymore ABSTRACT: Apparatus for ionizing gases at very low pressures comprising inner and outer electrodes wherein the inner electrode is substantially circular in cross section and the outer electrode surrounding the inner electrode may be other than a figure of revolution or may be eccentrically positioned with respect to the inner electrode which inner electrode is less in length than two times the length of the surrounding outer electrode and is spaced therefrom a distance which is greater than the diameter of the inner electrode for a distance of not less than two-thirds the length of the surrounding outer electrode.

SUWZ Y PATENTEU 19 3.614.440

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/ a 42 a 38 be a Z00 IN VI'IN'I '0 RV BARNEY J. CARR. DECEASED ELISABETH HELEN CARR ADMINISTRATOR FIG. IO. 2 Z 9129 ATTORNEYS GAS IONIZER DEVOID F COAXIAL ELECTRODES 1 This application is a continuation of application Ser. No. 404,535, filed on Oct. 16, 1964 and now abandoned.

Gas ionizers are used in such diverse types of apparatus as ion accelerators, ionic propulsion devices, high vacuum pumps and vacuum gauges. Apparatus presently available for ionizing gases for such applications, when the gases are at very low pressure, are relatively inefficient in terms of electrical energy input per ion produced. Even the most efficient ionizers require bulky and/or inefficient auxiliary equipment to provide the special environment needed for normal opera tion. In currently used ionizers such environments require radio frequency fields, magnetic fields, and/or electron or other charged particle beams from electrically heated filaments.

In contrast to such currently used ionizers, as described above, the apparatus of this invention employs neither an electrogenerating filament, nor a magnet, nor even a radiofrequency power source. The apparatus of the invention, therefore, eliminates all of the disadvantages incident to the use of such features. The invention rather employs a pair of electrodes, one within the other, in eccentric relation, with a low-pressure gas within the outer electrode and a relatively high voltage applied between the electrodes.

It has been suggested in the prior art that gas may be ionized, or a discharge effected through ionization, by the use of apparatus similar to that so broadly defined as charac teristic of this invention. For instance, in Reviews of Modern Physics, Volume 12, Apr. 1940, at pages 87-174, there appears an article by Druyvesteyn and Penning titled The Mechanism of Electrical Discharges in Gases of Low Pressure." Particularly at pages 121-123 of that article there are reported experiments with determination of the breakdown potential of gases at relatively low pressure between coaxial cylinders. FIG. 35 of the article illustrates the effect of the use of rather high ratios of electrode sizes and indicates that breakdown (formation of ions) was obtained with a ratio of 300 when the voltage between electrodes reached 2,000 volts, with a gas pressure of about 0.04 millimeters of mercury. Further, the figure indicates that the breakdown voltage increases very steeply as the pressure is reduced below 0.03 millimeters of mercury. in contrast to the teaching of the Druyvesteyn and Penning article, with the apparatus of the present invention, it has been found possible to obtain ionization, and consequent discharge, at pressures substantially lower than 0.001 millimeters of mercury and with breakdown voltages or starting potentials below 1,000 volts. The present invention evidently achieves such unexpected effect primarily by a process best termed as orbital trapping of electrons within the apparatus. This phenomenon is an incident of the use of extremely low pressure and very large ratios of electrode sizes and its effect in increasing the lengths of electron paths is further increased by axial trapping of the electrons achieved by urging the orbiting electrons away from the axial ends of the apparatus. The combined orbital and axial trapping effects increase the path lengths of electrons to such great, extent that the likelihood of their causing an ionization event is very greatly increased.

The axial trapping effect can be obtained either by supplying an auxiliary electrode biased to cathode potential, or more negatively, or by provision of axial terminations of the outer electrode which, together with the wall portion of that electrode substantially completely enclose the discharge space.

The use of coaxial electrodes at very low gas pressure has also been suggested by L. G. Guseva in the publication Radiotekhnika i Elektronika" Volume 4, No. 8, pages 1260-1268 (1959). This article, titled Discharge Ignition in Inhomogeneous Fields at Low Gas Pressure examines the effect of various electrode configurations with varying distances therebetween, one of such geometries employing a coaxial configuration. FIG. 5 of the article indicates that discharge was obtained for coaxial configuration at a pressure of 0.003 millimeters of mercury at about 2,000 volts, but like the Druyvesteyn and Penning disclosure, the experimental results reported in this Russian publication indicate that the starting potential, or breakdown voltage, rises very sharply below this pressure. In contrast to this teaching, it has been found that the apparatus of this invention can achieve discharge at even lower pressures than those reported by the Russian publication, and at lower voltages. This is perhaps explained by a difference in the ratios in the electrode size between that used by Guseva and those employed in this invention. The Guseva publication does not suggest such ratio, but it has been found very important to successful operation of this invention at very low pressures that the ratio be at least :1 and preferably greater than 1,00021. Moreover, though the Russian publica tion suggests substantially complete enclosure of the gas environment by the outer electrode, the termination of the inner electrode or the connection therefrom to the voltage supply, is shown as within the outer electrode and as being relatively large in size. The theory to be detailed subsequently in explanation of the probable reason for operation of this invention indicates that these features of the Russian apparatus would result in electrons which orbiting close to the wire or inner electrode being drawn to the terminations, resulting in substantial loss in the average path length of such electrons and thereby decreasing the probability of ionization therebyv It has been further suggested that discharge be effected at very low pressures with a coaxial configuration in Gale U.S. Pat. No. 2,907,884, issued Oct. 6, 1959. This patent, however, suggests that at very low pressures of the order of those preferred in the operation of this invention, the mean free path of the electrons is much larger than the dimensions of the ionization compartment, so that any ionization produced in the gas would be negligible without the use of a magnetic field. In contradistinction to this disclosure, it has been found that, though the ionization mean free path of 100 electron volt electrons in the apparatus of the invention is greater than the dimensions of the outer electrode, a very high level of ionization can be obtained without the use of any magnetic field.

The Gale patent also suggests the use of apertured discs attached to the outer electrode, but no indication is given of the size of the apertures in such discs and the discs are, in fact, employed for an entirely different purpose than the end plates forming axial terminations of the outer electrode of one embodiment of this invention. Moreover, it has been found that the size of any aperture in any such end plates, or indeed in the entire outer electrode, is extremely important to operation of the invention, and in fact the size of any such aperture should be less than half the size of the cross-sectional area embraced by the outer electrode, unless some other means (such as the suitably biased auxiliary electrode mentioned above) is used to compensate for any larger aperture.

It is a prime object of the present invention to obtain ionization of very low pressure gases without the use of any mag netic field and with less stringent electrode positioning than with prior art devices. A further object of the invention is to obtain such ionization at lower breakdown or starting potentials than indicated in the prior art. Another object of one embodiment of the invention is to achieve such ionization with an extremely simple apparatus employing only a pair of electrodes, a gastight enclosure and a voltage source. Such apparatus will be hereinafter described in detail in connection with its application as a neutron generator, but it may as well be employed in an ultra-high vacuum pump, a vacuum gauge, or an ionic propulsion engine.

In its application as a pump, the apparatus of the invention would function similarly to the well-known Varian Vac-Ion pump, but without the use of the magnetic field employed in such pump. In other words, the present apparatus would function to reduce the pressure in an enclosure to an extremely low level by such phenomena as cathode sputtering, gettering and the like. It is known that a vacuum pump employing the apparatus of the invention is capable of pumping down from an initial pressure of 0.01 millimeters of mercury to a final pressure of0.0001.

In its application to vacuum gauging, the apparatus of the invention would rely upon the dependence on gas pressure of the voltagetcurrent characteristics of the glow discharge of the invention, the voltage across the electrodes or the current between the electrodes being employed as an indication of such pressure.

The apparatus of the invention will also operate to achieve other functions where a source of ions from a gas is necessary, such applications being clear to any person familiar with gaseous electronics and knowing of the principles of the present invention.

As indicated, the apparatus of the invention, generally speaking, includes an outer and an inner electrode, the outer electrode defining a space within which a gas under very low pressure is confined and the inner electrode being eccentri cally located therein. The outer electrode may be a figure or a nonfigure of revolution configuration and may be unsymmetrical. The apparatus is also provided with means for urging orbiting electrons inward from the opposite ends of the electrodes, which means may include an auxiliary electrode suitably biased, or a construction of the outer electrode such as to substantially completely enclose the discharge space. The enclosure is then such that any aperture through the outer electrode is of a size substantially smaller than the major diameter of the outer electrode and preferably less than onehalf that size. A voltage source is connected to the electrodes, preferably with the inner electrode positive, to bias the elec' trodes to a voltage at least as high as the starting potential of the discharge, and the gas pressure within the apparatus is low enough in comparison with the outer electrode size that the ionization mean free path of lelectron-volt electrons within the outer electrode is larger than the major diameter of the outer electrode. If it is necessary to remove ions from the enclosure defined by the outer electrode, perforations may be provided either in one or more of the end portions of the outer electrode, or in the wall portion thereof, and ions may be urged away from the ionization region by development of a suitable electric field, as with a third spaced electrode biased negatively with respect to the electrodes of the discharge apparatus. That electrode may then function as the auxiliary electrode to urge orbiting electrodes inward from the adjacent end of the discharge space. A further and quite important object of the invention is to provide an improved ion generator design which can tolerate substantial leeway in manufacturing tolerances such as to permit the successful application of production line methods of assembly.

The apparatus of the invention will now be more fully described in conjunction with drawings showing preferred embodiments thereof and explaining the manner in which the apparatus is believed to operate.

In the drawings:

FIG. 1 is a longitudinal sectional view of a preferred embodiment of the invention employed as an ion source in a neutron generator;

FIG. 2 is a cross-sectional view taken along line 2-2 of FIG. 1.

FIG. 3 is a diagrammatic showing of a pair of coaxial cylindrical electrodes used to explain the manner in which the apparatus of the invention is believed to operate;

FIG. 4 is a diagrammatic showing of the force fields and equipotential lines obtained with coaxial electrodes without end plate terminations;

FIG. 5 is a diagrammatic showing of the same fields and lines obtained with the use of end plates as in the present invention;

FIG. 6 shows a plurality of graphs of starting potential versus pressure in the apparatus of the invention illustrating the effect of change in size of a central aperture through an end plate;

FIG. 7 shows various graphs of the starting potential of the discharge in the apparatus of FIG. 1, versus the gas pressure therein, with different ratios of sizes of the electrodes; and,

FIGS. 8, 9 and 10 are a diagrammatic illustration of the various eccentric, figure and nonfigure of revolution configurations which the device of this invention may take.

Referring now to FIG. 1, there is shown a generator according to the present invention generally indicated by reference numeral 10. The generator includes an inner electrode 12 in the form of a fine wire electrically attached in suitable manner to feed through conductor 14, which extends through a highvoltage insulator 16 positioned in a circular end closure 17 comprising one end plate of the hollow cathode l8. Wire I2 is of a diameter very much smaller than the inner diameter of the smallest wall portion of the cathode 18. Though the wire preferably functions as an anode and the outer electrode functions as a cathode, it is possible to operate the apparatus with the opposite use of the electrodes, though with a very much higher breakdown or starting potential.

It will be noted that the inner electrode 12 extends outside of the cathode l8 and is there connected to a voltage source as will be described hereinafter. At the opposite end from such connection and from the insulator 16, the cathode is terminated by a conductive screen or grid 20 which is formed of spaced wires. Also spaced from the end plate 20 is a target electrode 22 sealed to an insulating gastight envelope 24. The envelope 24 is also sealed to the cathode at 26, and in use of the apparatus the assembly is first highly evacuated and then backfilled with a gas at an extremely low pressure by means of gas source 28.

A suitable high-voltage supply 30 of conventional wellknown character is connected to the electrodes of the apparatus, with positive terminal 32 connected to anode l2 and negative terminal 34 connected to cathode 18. The target electrode 22 is connected to negative terminal 36 which biases that electrode to a voltage more negative than that on the cathode 18.

The ionizer itself consists of the anode 12 and the cathode wall structure 18, together with its end plates or terminations including the grid 20. The space between the grid or screen 20 and the target 22 is a drift space in which ions produced in the ionizer are accelerated to increase their energies prior to impact on the target 22. In use of the apparatus of FIG. 1, when a voltage as high as the starting potential at the particular pressure within the ionizer is applied between the anode and cathode, breakdown and self-sustained ion regeneration occurs to cause a glow discharge. lf, for instance, deuterium is confined within the ionizer, and the target electrode 22 is loaded or in some other manner caused to contain tritium, the deuterium ions from the ionizer will be accelerated toward the target 22 and impinge thereon to release neutrons. It will also be understood that deuterium could be employed in both the target and the ionizer, and other combinations of target material and gas filling could be used, including tritium in the ionizer and deuterium as the target load.

An explanation will now be given for the manner in which the present invention is believed to operate to produce the unexpected discharge at such low pressures and with such relatively low starting voltages. As an aid to consideration of the phenomena here involved, and in the interests of simplicity, reference will be made to FIG. 3 in which an outer cathode is formed by a hollow uniform circular cylinder C and an inner anode is formed by a uniform circular cylindrical structure. While this consideration involves the use of uniform circular cylinders for both the anode and the cathode, for purposes of explanation, it will be understood that the invention will operate with many other configurations, Contrary to prior art devices which in order to work most efficiently required that the cathode be of a figure of revolution configuration and the anode is a relatively thin rod positioned close to the axis of the cathode to extend parallel thereto, as illustrated in FIGS. 8 and 9, it has been found that the ionizer of this invention may advantageously have the anode A positioned eccentric within the cathode C which may be a nonfigure of revolution pro vided the length la of the anode A is less than two times the length 10 of the cathode chamber C and the distance from the anode to the cathode wall d is greater than the diameter of the anode A, d dww, and this distance, d, between the anode and cathode is maintained for not less than two-thirds the length of the anode la. For convenience in explanation of the operation of the apparatus, however, the uniform circular cylinder configuration will be utilized.

The equations of motion in cylindrical coordinates r, 0, z in an electric field represented by a potential function V (r, 6, z)

The field is evidently symmetrical, with the structure of FIG. 3, and it is assumed that the cathode is at a negative direct current potential in respect to the anode, so that the electrons are drawn inward by the electric forces. With the z coordinate axis taken along the electrode axis, the potential V 18 independent of 6 because of the assumed electrode symmetry. Accordingly, equation (2) above can be integrated yielding the basic equation:

mr(d6/dt)=P (4) where P is a constant of the motion expressible in terms of the initial conditions in the form:

P=mr (d6/dI) (5) By means of equation (4), the term dB/dr may be eliminated from equation I yielding:

2 I r Jfi 1ii; ;'T [2mr (6) Equations (3) and (6) suffice to determine both r(t) and (2) in terms of the initial conditions and once r(I) is known 8(t) can be obtained from equation (5) by an integration with respect to time. For our purpose, however, detailed orbit cal culations are not required and the desired information can be obtained by means of partial integration of equations (3) and (6) which yield the following equation:

E==( 1/2 )m[(dr/dt) l-(dz/dt) ]+(P /2mr )+eV(r, z) (7) In this equation E is a constant of the motion expressible in terms of the initial conditions in the following form:

E=( l/2)m[(dr/dt)-l*(dzldt) ]+(P/2mr )+eV(r 1 (8) where the subscript 0 indicates the initial condition.

Inspection of equations (3) and (6) indicates that the motion in the r, z plane is determined by an effective potential W(r, z) defined as follows:

W(r, z)'=(l/2mr )+eV(r, z) (9) Wis actually a potential energy in the rz plane, while the other portion of equation (8) represents the kinetic energy in that lane.

p It will be appreciated that motion does not take place in any part of the rz plane in which the kinetic energy is negative. In other words, points r, z are accessible only if:

E Z W(r, z) 10) Looking at this another way, any point is inaccessible if:

W(r, 2) E E (11) Considering the anode, and using its radius as a, the general condition that the anode be inaccessible is:

PIZma 13 (12) (we have assumed that the arbitrary 0 of electrostatic poten' tial, V, is placed at the anode which assumption is valid since we consider only cylindrical anodes and therefore V=0 at r==a The potential V(r) for a long cylindrical cathode as shown in FIG. 3 is the following, since the z dependence of V is negligible:

V(r)=V(b)[ln(b/a]ln(r/a) (13) where a and b are the anode and cathode radii, respectively, and V(b) is the potential of the cathode relative to the anode.

The form of W(r) can be plotted and it will be found that it has a minimum at a radius r,,, whenever P is not equal to zero. When that radius is between the outside surface of the anode and the inside surface of the cathode, there exists a set of values of E for which any electron in the space between the anode and cathode cannot reach the cathode. Those values are defined by the equation:

in.) 3 Wu: (P/2mb)+eV(b) 14 Further, there is an overlapping set of values of E for which the particle cannot reach the anode. Those values are defined by the equation:

When both of the inequalities (l4) and (15) are satisfied, the particle can reach neither of the electrodes and the electron may be said to be radially trapped. The region of the rz plane which meets the necessary condition for accessibility given by equation 10), I term the allowed zone.

The utilization of the above equations and reasoning in explanation of the apparent operation of the apparatus of the invention may be effected by consideration of an electron which is released, as by ionization, at a position 0 shown in FIG. 3 and having initial r and 2 positions r and z, and with an initial velocity v at an angle a relative to the rz plane. Under such conditions,

Substitution of these equations in the inequality (12) yields the following equation:

sin a sin w in this equation the angle a, is the critical angle of emission of an electron relative to the rz plane above which the electron will not strike the anode. If it be assumed that the electrodes are long and are uniform circular cylinders, the z dependence of V can be neglected throughout most of the volume and V is given by equation (13) Substituting this value in equation (18), assuming that typical secondary electrons formed in the space between the electrodes have an initial energy (ll2)mv {=10 electron volts, choosing V(b) as 1,000 volts and the ratio of the cathode radius to the anode radius bla=l ,000, the following values of a,- may be obtained for different distances between the anode and cathode.

Examination of these critical angles together with a corresponding table of critical angles for cathode inaccessibility based on equation (14) indicates that IO electron volt ionization secondary electrons emitted throughout percent of the volume between the anode and cathode would be radially trapped in at least 90 percent of the ionizing events, assuming random initial directions of motion. With such secondary electrons radially trapped, those electrons would orbit the anode over extremely long path lengths until the electrons were deflected by collision with gas molecules. Such a collision would often merely deflect the primary electron into a different orbit, while the secondary electron from an ionization event would itself go into a radially trapped orbit. A cascade process results in which a single electron may cause a large number of ionization events, which in turn result in a further large number of ionization events, and a breakdown or discharge occurs. This type of cascade process is termed an orbital cascade." The mathematical analysis is found to apply in an almost identical manner to an eccentrically positioned anode arrangement.

Most secondary electrons formed by the bombardment of the cathode by positive ions would make one orbit of the anode and return to the cathode, thus reducing the current drain in the apparatus and increasing the efficiency thereof.

The probability of the trapping effect occurring, and its resultant enhancement of ionization probability, have been found to be directly affected by change in the cathode to anode dimension ratio. If the same equation (18) were employed with a b/a ratio of 100, and a table similar to table 1 derived, it would be seen that the critical angles would be very much larger than indicated in that table. However, it would also be seen that radial trapping would occur with such a ratio, but if the ratio were reduced to an even smaller figure, the likelihood of enhancement of ionization by the trapping effect would diminish very rapidly.

Referring now to FIG. 4, it will be seen that the electric field of force tends to urge electrons orbiting the anode out through the end of the cathode, if the cathode is open at its axial ends. In contrast, the comparable force vectors with the axial terminating end plates of FIG. tend to urge electrons which have approached the axial ends of the cathode back toward the center of the space within the cathode. This effect is obtained by virtue of the end plates being connected to and forming parts of the cathode. It will be noted that these plates have apertures therethrough which may be employed, for instance, to provide for terminations of the anode wire and connection of that wire externally of the cathode to the voltage supply. Such apertures may also be employed so that positive ions developed by ionizing events within the cathode may be urged out of that space for use externally thereof. The size of these apertures has been found to be very important to the operation of the invention, because the larger size, the smaller the effect of the forces tending to prevent orbiting electrons from leaving the cathode space, and the resultant diminishment of the probabilities of ionization by such electrons. FIG. 6 shows this effect, with the starting potential at which the discharge occurs plotted against the gas pressure in millimeters of mercury, for several different diameters of apertures through end plates. It will be seen that the curves a, b and 0, (respectively for one-eighth, one-fourth and three-eighths of the cathode diameter) are generally of the same shape, with the starting potential gradually increasing as the aperture size is increased. However, curve d using an aperture only one-half as large as the cathode diameter is of an entirely different shape requiring very much higher starting potentials to initiate the discharge. Curve e shows the deleterious effect of nonuse of end plates. It will be apparent from consideration of these curves that it is preferred that any aperture leading out of the space bounded by the cathode be not more than one-half the size of the cross-sectional area bounded by the cylindrical wall portion of the cathode. However, as noted above, the deleterious effect of any larger aperture may be at least partially compensated for by use of an auxiliary electrode biased to the same or a more negative potential than the cathode and positioned externally to such aperture. Thus, for example, in the embodiment wherein the target electrode 22 is biased negatively with respect to the grid 20 the grid might be eliminated leaving a completely open end aperture in electrode 18. In such case the target electrode would serve the purpose of urging orbiting electrons into the interior of electrode 18, in lieu of the grid.

The curves shown in FIG. 7 are of the type generally referred to as Paschen Curves," being plots of the starting potential of the gaseous discharge versus the pressure of the inner electrode environment. The curves shown were taken with respect to an ionizer having a cylindrical cathode with an inside'diameter of 4.7 centimeters and a length of 5.1 centimeters, and with end closures centrally perforated by holes or apertures of 0.635 centimeters diameter. Deuterium was used as the discharge gas.

Those familiar with Paschen Curves for other electrode configurations will immediately notice that, considering the range of starting potentials shown, the curves lie in a region of much lower pressure than those usually encountered, in particular with a parallel plate electrode configuration of comparable dimensions. In other words, with the apparatus of the present invention, it is possible to obtain a discharge at relatively convenient potentials of the order of 2,000 volts, or less, and at very much lower pressures than is possible with other electrode configurations. The extremely low operating pressure is a very important feature of the invention, for one reason because it allows the ion source to be physically com bined with the drift space of an ion accelerator, operating at the same low pressure, and without significant energy degradation of the ion beam due to charge exchange collisions of ions from the source with gas molecules in the drift space of the accelerator.

The criterion that must be fulfilled in order that drift space collisions will not significantly degrade the performance of a neutron-producing accelerator is that the product ps, where p is the gas pressure in the drift space in millimeters of mercury (mm. Hg) and s is the length of the drift space in centimeters (cm.), must be less than 4X10". At the same time, in order that spurious vacuum sparking across the drift space may be avoided at the high drift space potentials (I00 to 200 kilovolts) required for optimum neutron yields, it is necessary that the space s be longer than 2 cm. Hence the above condition on the product ps can be fulfilled only ifp is less than 2X10 mm. Hg. In contrast to most ionizers of the prior art, the ionizer of this invention not only operates readily at this pressure, but will operate at much lower pressure with no difficulty. Consequently, using the ionizer of this invention, a neutron-producing accelerator of maximum efficiency can be combined therewith without incorporating a pump to provide pressure differential between the ionizer and the drift space.

Although performance of comparable merit can be obtained through use of a Penning-type ion source (one effecting a cold cathode discharge through use of a magnetic field), this type of source requires the use of a magnet. The elimination of the necessity for magnets provided for by this invention is a considerable advantage, particularly when a system of minimum size, weight and cost is required.

The curves of FIG. 7 also show the effects of changing the diameter of the anode while the cathode size and configuration remain constant as above defined. The curve labeled a was obtained with apparatus using a wire anode having a diameter of 0.001 inch. Curve b shows the efi'ect of increasing the anode diameter to 0.005 inch. Curves a and b are similar in that the starting potential varies only slightly over a considerable range of pressure. However, when the anode diameter was increased to 0.02 inch, the starting potential at the minimum pressure plotted was about eight times the starting potential at the corresponding pressure for which discharge was obtained with the 0.00l-inch anode. These effects are shown in curve c, and in obtaining that curve it was impossible to cause a discharge at pressures lower than the minimum indicated at the curve.

The mathematical explanation for the increase in minimum pressure at which discharge can be obtained, as the anode size is increased with respect to cathode size. will be apparent from the equations derived above. The physical explanation for the phenomenon apparently is that, as the anode increases in size, it intercepts orbiting electrons at earlier stages of their orbits. The total path length of the individual electron is therefore decreased and the probability of collision with a gas molecule is correspondingly decreased. Therefore, with a given applied potential, a higher pressure is required to increase the number of gas molecules present and therefore enhance the probability of an ionizing collision enabling initiation of the discharge. The orbital cascading process in the ionizer of the invention is very materially reduced if the wire diameter is larger than onehundredth of the diameter of the wall portion of the cathode. Nevertheless, for some purposes, for instance where a very high ion yield is required and power efficiency is of secondary importance, a wire diameter as large as one-tenth of the diameter of the cathode might be employed. Even in such case all of the efiects of the orbital cascade described herein would not be lost.

It will also be understood from the mathematical analysis above provided that the prolonged electron path length which results from the electron orbiting phenomenon with respect to the anode greatly increases the probability that an electron will undergo an ionizing collision with a gas molecule. This feature permits the discharge to sustain itself in the ionizer of the invention at pressures so low that the ionization mean free path for electrons is hundreds of times the length of the intern lectrode spacing. It will be understood that the ionization mean free path depends on the energy of the electrons, as well as the pressure of the gas, so that the criterion correlating the electron mean free path and the size of the cathode and the pressure is herein stated in terms of electrons of IOU-electronvolt energy.

in the case of a figureof-revolution cathode with a coaxial anode wire, the allowed radial zone of motion is fixed by the initial conditions. When the allowed zone excludes the wire and the cathode an indefinite periodic oscillation occurs, which oscillation cannot intercept an electrode until a scatter ing between the electron and a gas molecule changes the allowed zone. When the allowed zone excludes the wire, as it does in the case of most secondary electrons from the cathode, but includes some part of the cathode, as in the case of all cathode secondaries, the electron will never hit the anode without at least one gas scattering, but until such scattering occurs the cathode remains energetically accessible. If the cathode is an infinite-length cylinder, unscattered secondary electrons from the cathode will always retum thereto after one swing around the wire anode, unless they contact the latter. When the ends of a finitedength cylindrical cathode are closed by apertured plates, the electron will always return to the cathode if it fails to scatter, but several radial oscillations can occur in many cases before such return. This effect also increases the probability of ionization during the travel of such an electron.

in the preferred embodiment of the invention as described hereinabove, the cathode is a hollow cylinder closed at its ends to prevent loss of electrons with the anode positioned eccentrically therein. The anode is positioned to provide for minimum capture of theelectrons and contrary to prior art thinking the anode need not be positioned close to the axis of the cathode and parallel thereto to achieve this criteria. The electrical field between the anode and cathode need not be i too symmetrical to provide ample orbiting of electrons.

Further, the cathode may be a nonfigure of revolution itself unsymmetrical and achieve the improved results. The anode is desirably as small as possible consistent with the desired high ratio of the major diameter of the cathode wall portion to the thickness of the anode. Ordinarily therefore, the smallest wire which will not melt at the required level and duration of ion production will be employed as the anode.

It will be understood that the inner electrode 12 of the preferred embodiment may be supported by means of a small insulator mounted on cathode 18 or grid 20 to provide mechanical stability. It will also be seen that an ionizer having a series of continuous anodes eccentrically positioned within an extended cathode could be fabricated without difficulties in providing structural support. Such a zigzag anode arrangement is diagrammatically illustrated in FIG. wherein only the cathode 18a and anode 12a are shown, with anode 12a supported at spaced points along the cathode by insulators 38. Of course, the other requirements of the length of the anode with respect to the enclosing length of the cathode chamber and the distance of the anode from the cathode with respect to the diameter of the anode with this distance being maintained for not less than two-thirds of the length of the cathode chamber must be met. The positioning of the anode eccentrically with respect to the cathodes permits the extraction of ions other than axially such that a larger extraction window or aperture is available within a given space. With the configurations of the present invention it is possible with a design like that of FIG. 10 to provide an increase in ion population on the order of from three to five times that available with the coaxial configurationof prior art devices.

The objectives of the invention are best obtained when the diameters of the ionizer, and the pressure of the gas therein, are such that the product pr is less than a quantity x, where x==0.l if the gas is hydrogen or an isotope thereof and the pressure (,0) is in millimeters of mercury and the major spacing of the cathode (r) in centimeters. This relationship is approximately the same as the criterion that the ionization mean free path of lOO-electron-volt electrons be greater than the major diameter of the cathode. The quantityx in the former relationship varies by a factor of about 13 when different gases other than hydrogen and its .isotopes are employed.

It will be understood by those skilled in the art that the discharge obtained with the apparatus of this invention is not of the well-known Townsend type, since such discharge requires a pressure much higher than that at which the apparatus of this invention is capable of operating.

it will be apparent from the above that many changes can be made in the apparatus of the invention without departure'from its scope. The invention is therefore not to be considered limited to the preferred embodiment disclosed herein, but rather only by the scope of the appended claims.

What is claimed is:

l. A gas ionizer adapted to ionizing a gas without the use of a magnetic field which comprises,

a first metal electrode having a hollow wall portion defining a chamber,

a second metal electrode of rod shape eccentrically posi tioned a substantial amount with respect to the walls of said wall portion to be in substantial axial misalignment therewith, the cross-sectional size of said second electrode being very much smaller than the cross-sectional area within said wall portion,

means for biasing one of said electrodes negatively with respect to the other to a high voltage,

means for providing an environment of said gas at very low pressure within the chamber bounded by said first electrode, the pressure of said gas and the dimensions of the wall portion of the first electrode being such that the ionization mean free path of l00-electron-volt electrons in said gas is greater than the largest inside cross-sectional dimension of said wall portion,

the said voltage being higher than the starting potential of ion discharge in the said apparatus,

and means extending at least part way across the chamber bounded by said first electrode for urging electrons adjacent the opposite ends of said first electrode inwardly away from such ends.

2. The apparatus of claim 1 wherein the length of the second electrode is less than about two times the length of the chamber defined by the hollow wall portion of said first electrode and the second electrode is spaced from said wall portion for at least about two-thirds of its length by an amount at least substantially greater than the cross-sectional size of said second electrode.

3. The apparatus of claim 2 wherein the length of the second electrode is greater than the length of the chamber defined by the hollow wall portion of the first electrode.

4. The apparatus of claim 2 in which said urging means includes an auxiliary electrode positioned adjacent one of the ends of said first electrode and biased to a negative voltage at least as large as that on said one electrode.

5. The apparatus of claim 2 in which said urging means includes terminations of said first electrode of configuration such that the first electrode substantially completely encloses a discharge chamber with any opening through said first electrode of size much smaller than the maximum cross-sectional area within said hollow wall portion.

6. The apparatus of claim 4 in which said urging means further includes an axial termination for the end of said first electrode opposite the end adjacent said auxiliary electrode, said first electrode substantially completely enclosing a discharge chamber having no opening through the first electrode of size greater than one-half of the cross-sectional area within said hollow wall portion, except at its end adjacent said auxiliary electrode.

7. The apparatus of claim 5 in which said biasing means includes a source of high voltage and connections between said source and said electrodes, the connection to said second electrode being outside of said chamber defined by the first electrode. a

8. The apparatus of claim 5 in which said first electrode is a cathode biased negatively with respect to said second electrode, forming an anode.

9. The apparatus of claim 8 in which said cathode has a grid end member formed of spaced wires defining an axial termination of said wall portion thereof.

10. The apparatus of claim 8 in which said cathode has an end member defining a termination of said wall portion thereof, said end member having an aperture therethrough less than one-half as large as said cross-sectional area bounded by the wall portion of the cathode.

11. The apparatus of claim 8 in which the pressure of said gas in millimeters of mercury and the major spacing of the anode from the wall portion of the cathode in centimeters are such that their product is less than 0.1 for hydrogen and isotopes thereof.

12. The apparatus of claim 8 in which said anode is a straight cylindrical wire of such diameter thatthe major inside dimension of said cathode is more than 100 times as large thereas.

13. The apparatus of claim 12 in which the major dimension of the cathode is more than 1,000 times as large as the diameter of said wire anode.

14. The apparatus of claim 8 including a third electrode spaced from said anode and cathode and within the environment of low-pressure gas,

and means biasing said third electrode more negatively than said cathode to attract positive ions from the chamber within said cathode.

15. The apparatus of claim 8 wherein the anode is of a zigzag configuration within the chamber defined by the cathode.

16. Apparatus effective in ionizing a gas without the use of a magnetic field comprising,

a hollow metal cathode having a wall portion with end members defining terminations thereof and joined thereto, said end members and said wall portions substantially completely enclosing a space therewithin with any opening therethrough being of a size with is much smaller than the major sectional area within said wall portion, Crosssectional a cylindrical wire anode eccentrically positioned in and extending substantially through the entire length of the cathode to be in substantial axial misalignment therewith, the major inside dimension of said cathode being at least 1,000 times as large as the diameter of said anode,

a gastight enclosure around said cathode confining gas under very low pressure therein, the pressure of said gas in millimeters of mercury and the spacing between the anode and cathode in centimeters being such that their product is less than a quantity X, where X=0.l for hydrogen and isotopes thereof and varies by a factor of about 13 depending upon the nature of the gas employed in the apparatus,

and means for biasing the cathode negatively with respect to the anode to a voltage higher than the starting potential of ion discharge in the said ap aratus. 17. The apparatus of claim 6 in which the cathode has at least one aperture therethrough of a size which is less than one-half as large as the major cross-sectional area bounded by said cathode,

a third electrode spaced from said anode and cathode and within said gastight enclosure,

and means for biasing said third electrode to a voltage more negative than that of said cathode.

18. The apparatus of claim 17 in which said third electrode carries a material operative to produce neutrons when struck by positive ions developed from said gas.

19. The apparatus of claim 16 in which the anode is less than about two times the length of the chamber defined by the cathode and is spaced from said cathode for at least about two-thirds of its length by an amount at least substantially greater than the cross-sectional size of the anode. 

1. A gas ionizer adapted to ionizing a gas without the use of a magnetic field which comprises, a first metal electrode having a hollow wall portion defining a chamber, a second metal electrode of rod shape eccentrically positioned a substantial amount with respect to the walls of said wall portion to be in substantial axial misalignment therewith, the cross-sectional size of said second electrode being very much smaller than the cross-sectional area within said wall portion, means for biasing one of said electrodes negatively with respect to the other to a high voltage, means for providing an environment of said gas at very low pressure within the chamber bounded by said first electrode, the pressure of said gas and the dimensions of the wall portion of the first electrode being such that the ionization mean free path of 100-electron-volt electrons in said gas is greater than the largest inside cross-sectional dimension of said wall portion, the said voltage being higher than the starting potential of ion discharge in the said apparatus, and means extending at least part way across the chamber bounded by said first electrode for urging electrons adjacent the opposite ends of said first electrode inwardly away from such ends.
 2. The apparatus of claim 1 wherein the length of the second electrode is less than about two times the length of the chamber defined by the hollow wall portion of said first electrode and the second electrode is spaced from said wall portion for at least about two-thirds of its length by an amount at least substantially greater than the cross-sectional size of said second electrode.
 3. The apparatus of claim 2 wherein the length of the second electrode is greater than the length of the chamber defined by the hollow wall portion of the first electrode.
 4. The apparatus of claim 2 in which said urging means includes an auxiliary electrode positioned adjacent one of the ends of said first electrode and biased To a negative voltage at least as large as that on said one electrode.
 5. The apparatus of claim 2 in which said urging means includes terminations of said first electrode of configuration such that the first electrode substantially completely encloses a discharge chamber with any opening through said first electrode of size much smaller than the maximum cross-sectional area within said hollow wall portion.
 6. The apparatus of claim 4 in which said urging means further includes an axial termination for the end of said first electrode opposite the end adjacent said auxiliary electrode, said first electrode substantially completely enclosing a discharge chamber having no opening through the first electrode of size greater than one-half of the cross-sectional area within said hollow wall portion, except at its end adjacent said auxiliary electrode.
 7. The apparatus of claim 5 in which said biasing means includes a source of high voltage and connections between said source and said electrodes, the connection to said second electrode being outside of said chamber defined by the first electrode.
 8. The apparatus of claim 5 in which said first electrode is a cathode biased negatively with respect to said second electrode, forming an anode.
 9. The apparatus of claim 8 in which said cathode has a grid end member formed of spaced wires defining an axial termination of said wall portion thereof.
 10. The apparatus of claim 8 in which said cathode has an end member defining a termination of said wall portion thereof, said end member having an aperture therethrough less than one-half as large as said cross-sectional area bounded by the wall portion of the cathode.
 11. The apparatus of claim 8 in which the pressure of said gas in millimeters of mercury and the major spacing of the anode from the wall portion of the cathode in centimeters are such that their product is less than 0.1 for hydrogen and isotopes thereof.
 12. The apparatus of claim 8 in which said anode is a straight cylindrical wire of such diameter that the major inside dimension of said cathode is more than 100 times as large thereas.
 13. The apparatus of claim 12 in which the major dimension of the cathode is more than 1,000 times as large as the diameter of said wire anode.
 14. The apparatus of claim 8 including a third electrode spaced from said anode and cathode and within the environment of low-pressure gas, and means biasing said third electrode more negatively than said cathode to attract positive ions from the chamber within said cathode.
 15. The apparatus of claim 8 wherein the anode is of a zigzag configuration within the chamber defined by the cathode.
 16. Apparatus effective in ionizing a gas without the use of a magnetic field comprising, a hollow metal cathode having a wall portion with end members defining terminations thereof and joined thereto, said end members and said wall portions substantially completely enclosing a space therewithin with any opening therethrough being of a size with is much smaller than the major sectional area within said wall portion, Cross-sectional a cylindrical wire anode eccentrically positioned in and extending substantially through the entire length of the cathode to be in substantial axial misalignment therewith, the major inside dimension of said cathode being at least 1,000 times as large as the diameter of said anode, a gastight enclosure around said cathode confining gas under very low pressure therein, the pressure of said gas in millimeters of mercury and the spacing between the anode and cathode in centimeters being such that their product is less than a quantity X, where X 0.1 for hydrogen and isotopes thereof and varies by a factor of about 13 depending upon the nature of the gas employed in the apparatus, and means for biasing the cathode negatively with respect to the anode to a voltage higher than the starting potential of ion discharge in the said apparatus.
 17. The apparatus of claim 16 in which the cathode has at least one aperture therethrough of a size which is less than one-half as large as the major cross-sectional area bounded by said cathode, a third electrode spaced from said anode and cathode and within said gastight enclosure, and means for biasing said third electrode to a voltage more negative than that of said cathode.
 18. The apparatus of claim 17 in which said third electrode carries a material operative to produce neutrons when struck by positive ions developed from said gas.
 19. The apparatus of claim 16 in which the anode is less than about two times the length of the chamber defined by the cathode and is spaced from said cathode for at least about two-thirds of its length by an amount at least substantially greater than the cross-sectional size of the anode. 